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Figure 6.1-14 To illustrate the molecular ( a )enhancement of SERS due to resonance Raman the scattering for excitation into a charge transfer band of the adsorbdte-meta~-surface-comp~ex filled n and empty n* orbital levels of pyridine and the metallic density of states of copper arc shown on the left- and right-hand side, respectively; for details see text (Creighton, 1986). A third way (Creighton, 1988) in which the surface may modify the intensity of Raman scattering by molecules adsorbed at the surface is by perturbing the molecules as a result of the bonding interaction with the surface. However, it turned out that this chemical effect on the Raman spectra is relatively small, and it is not normally considered to be a part of SERS, though it is inseparable from it. Several other SERS mechanisms have also been proposed (see for instance the discussion by Moskovits, 1985) which by now are widely thought to make at most only minor contributions to the enhancements observed in SERS. By the two strong-enhancement mechanisms as discussed above a number of features inherent in SERS can now be understood. They have been summarized by Creighton (1990). Finally, we notice that the selection rules for SERS are fundamentally the same

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which can be evaluated from (9.517) and (9.518). Using these exact results for the Weibull channels, approximate results for average combined SNR, SNR variance, and AF at the GSC output over i.i.d Nakagami, Rician, and Hoyt channels can be obtained by an AF-based mapping plotted in Figs. 2.2 and 2.3. As an example, Figs. 9.80 and 9.81 show the good match obtained for the normalized average combined SNR E[ GSC ]/ in heavier-than-Rayleigh fading (c = 1.75 or equivalently m = 0.76 and q = 0.53) and lighter-than-Rayleigh fading (c = 3 or equivalently m = 2.17 and K = 2.76) environments, respectively. In Figs. 9.80 and 9.81 the average combined SNR for Weibull fading is obtained from (9.517), whereas it is obtained via numerical integration for the Nakagami/Hoyt/Rice cases (with the appropriate mapping between the Nakagami/Hoyt/Rice and the Weibull fading parameters). As an additional numerical example, Fig. 9.82 quanti es the relatively signi cant diversity gain in the AF as L increases for a xed Lc compared to the small decrease of the AF as Lc increases for a xed L, especially as Lc approaches L. Note that in contrast to the normalized average combined SNR for which we had a good match between exact and approximate results for both the Rice and Nakagami models, Fig 9.82 shows that while the match is good for the Rician case, the AF values

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for the BEP of M-PSK in AWGN that is quite accurate at both low and high SNR and furthermore is valid for all M. In particular for M-PSK, it is shown [8] that Pb (E) = 2 max log2 M, 2

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